Advanced hemp-based hybrid composites: A study on the influence of various nanofillers on mechanical and morphological properties

Authors

  • Velmurugan GANESAN Department of Mechanical Engineering, School of Engineering, Mohan Babu University, Tirupati, Andhra Pradesh, India 517102;
  • Jasgurpreet Singh CHOHAN Department of Mechanical Engineering, University Centre for Research and Development, Chandigarh University, Gharuan Mohali, India- 140 413.
  • Muthukumar V Department of Mechanical Engineering, Saveetha Engineering College, Saveetha Nagar, Thandalam, Chennai – 602 105.
  • Nagaraj M Insitute of Agricultural Engineering, Saveetha School of Engineering, Saveetha Institute of Medical and Technical Sciences (SIMATS), Saveetha University, Chennai, Tamil Nadu, India-602 105
  • Lakshmi Narayana S Department of Mechanical Engineering, School of Engineering, Mohan Babu University, Tirupati, Andhra Pradesh, India 517102

DOI:

https://doi.org/10.55713/jmmm.v36i2.2427

Keywords:

Hemp fiber, Nanocomposites, Tensile properties, Aluminum oxide, Silicon dioxide, Magnesium oxide

Abstract

This study investigates the mechanical and microstructural attributes of epoxy composites with hemp fiber reinforcements and incorporated aluminum oxide (Al2O3), silicon dioxide (SiO2), and magnesium oxide (MgO) nanoparticles at different weight fractions of 0.5 wt%, 1.0 wt%, and 1.5 wt%. Nano-fillers remarkably improved the composite performance, as indicated by tensile and flexural tests conducted by ASTM D3039 and ASTM D790 standards. The composite containing 1.5 wt% Al2O3 outperformed other nano filled composites with a tensile strength of 64 MPa and tensile modulus of 3.6 GPa, versus 52 MPa and 3.0 GPa for the unfilled hemp/epoxy composite. In parallel, flexural strength and modulus also improved from 78 MPa and 3.5 GPa (unfilled) to 93 MPa and 4.2 GPa with 1.5 wt% Al2O3. SEM images corroborated the improved interfacial bonding and diminished fiber pull-out in nano-filled composites. The addition of nanofillers, mainly Al2O3, greatly improved the structural integrity of the hemp-based green composites, allowing for their use in sustainable load-bearing engineering applications.

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References

K. M. F. Hasan, P. G. Horváth, and T. Alpár, “Potential natural fiber polymeric nanobiocomposites: A review,” Polymers, vol. 12, no. 5, p. 1072, 2020. DOI: https://doi.org/10.3390/polym12051072

K. N. Keya, N. A. Kona, F. A. Koly, K. M. Maraz, M. N. Islam, and R. A. Khan, “Natural fiber reinforced polymer composites: History, types, advantages and applications,” Materials Engineering Research, vol. 1, no. 2, pp. 69–85, 2019. DOI: https://doi.org/10.25082/MER.2019.02.006

T. Mishra, P. Mandal, A. K. Rout, and D. Sahoo, “A state-of-the-art review on potential applications of natural fiber-reinforced polymer composite filled with inorganic nanoparticle,” Composites Part C: Open Access, p. 100298, 2022. DOI: https://doi.org/10.1016/j.jcomc.2022.100298

G. V. Jasgurpreet, S. Chohan, D. E. Raja, P. Paramasivam, and R. Maranan, “Thermo‑mechanical and flame‑retardant performance of epoxy/hemp composites reinforced with nano ‑ SiO2 and Al(OH)3,” Fibers and Polymers, vol. 26, no. 8, pp. 3601‒3620, 2025. DOI: https://doi.org/10.1007/s12221-025-01043-7

A. Shahzad, “Hemp fiber and its composites - A review,” Journal of Composite Materials, vol. 46, no. 8, pp. 973–986, 2012. DOI: https://doi.org/10.1177/0021998311413623

Y. Karaduman, H. Ozdemir, N. S. Karaduman, and G. Ozdemir, “Interfacial modification of hemp fiber–reinforced composites,” in Natural and artificial fiber-reinforced composites as renewable sources, Ed. Ezgi Günay, Turkey, 2018, pp. 17‒18. DOI: https://doi.org/10.5772/intechopen.70519

C. Ramanjaneyulu, S. Saravanan, G. D. Babu, and P. Prabhu, “Study on the engineering properties of abaca/hemp/kenaf natural fiber mats reinforced with Anogeissus latifolia, polyester resin, and fly ash nano powder nanocomposites,” Biomass Conversion and Biorefinery, vol. 15, no. 9, pp. 114047–14057, 2024. DOI: https://doi.org/10.1007/s13399-024-06096-x

J. Mohammed, M. Durga, J. Arputhabalan, N. Parthiban, R. Velumayil, G. A. Sivasankar, V. S. Rajput, and B. Palanikumar, “Enhancing mechanical properties of hemp fibre/epoxy hybrid nanocomposites through response surface methodology,” in AIP Conference Proceedings, vol. 3270, no. 1, p. 20248, 2025. DOI: https://doi.org/10.1063/5.0261761

V. Ganesan, J. S. Chohan, A. Damodharan, P. Paramasivam, and R. Maranan, “High-performance biocomposites: Leveraging lotus fiber and waste Kigelia pinnata fruit shell biochar for enhanced mechanical and fire-retardant properties,” Polymer Bulletin, vol. 82, pp. 3927–3961, 2025. DOI: https://doi.org/10.1007/s00289-025-05702-w

W. Li, B. Li, Y. Zhao, Y. Wang, H. Liang, and B. Lv, “Preparation of an Fe3O4 nanoparticle/carbonized hemp fiber composite with superior microwave absorption performance,” ACS omega, vol. 9, no. 49, pp. 48460–48470, 2024. DOI: https://doi.org/10.1021/acsomega.4c07063

P. Krishnasamy, G. Rajamurugan, A. Belaadi, and R. Sasikumar, “Dynamic mechanical characteristics of natural fiber hybrid composites, Bio composites and Nano composites–A Review,” Engineering Research Express, no. 1, p. 012503, 2024. DOI: https://doi.org/10.1088/2631-8695/ad2f86

P. S. Jadhav, A. Sarkar, L. Zhu, and S. Ren, “Flame retardant biogenic building insulation materials from hemp fiber,” Journal of Applied Polymer Science, vol. 141, no. 12, p. e55137, 2024. DOI: https://doi.org/10.1002/app.55137

A. Saha, “Polymer nanocomposites: A review on recent advances in the field of green polymer nanocomposites,” Current Nanoscience, vol. 20, no. 6, pp. 706–716, 2024. DOI: https://doi.org/10.2174/0115734137274950231113050300

S. K. Mani, S. Selvaraj, G. Sivanantham, F. S. Arockiasamy, J. Iyyadurai, and M. Mani, “Advancements in chemical modifications using NaOH to explore the chemical, mechanical and thermal properties of natural fiber polymer composites (NFPC),” International Polymer Processing, vol. 39, no. 4, pp. 406–432, 2024. DOI: https://doi.org/10.1515/ipp-2024-0002

V. Ganesan, and B. Kaliyamoorthy, “Utilization of Taguchi technique to enhance the interlaminar shear strength of wood dust filled woven jute fiber reinforced polyester composites in cryogenic environment,” Journal of Natural Fibers, pp. 1–12, 2020. DOI: https://doi.org/10.1080/15440478.2020.1789021

D. Shelly, S. Lee, and S. Park, “Hemp fiber and its bio-composites: a comprehensive review part I—characteristics and processing,” Advanced Composites and Hybrid Materials, vol. 8, no. 3, pp. 1–47, 2025. DOI: https://doi.org/10.1007/s42114-025-01314-0

R. Coşkun, A. Delibaş, and D. Y. Karanfil, “Metal ferrite supported bio-nanocomposite from hemp biomass and properties,” Biomass Conversion and Biorefinery, vol. 14, no. 16, pp. 18523–18537, 2024. DOI: https://doi.org/10.1007/s13399-023-03987-3

S. Bashir, M. A. Siddiqui, A. Al-Khedhairy, M. Girdhar, T. Malik, A. Kumar, and A. Mohan, “Herbicide-induced alterations in hemp fiber: A comparative analysis of strength and morphology,” Journal of Engineered Fibers and Fabrics, vol. 20, no. 9, p. 15589250251319320, 2025. DOI: https://doi.org/10.1177/15589250251319321

S. M. Shahabaz, P. Mehrotra, H. Kalita, S. Sharma, N. Naik, D. J. Noronha, and N. Shetty, “Effect of Al2O3 and SiC nano-fillers on the mechanical properties of carbon fiber-reinforced epoxy hybrid composites,” Journal of Composites Science, vol. 7, no. 4, p. 133, 2023. DOI: https://doi.org/10.3390/jcs7040133

A. Guchait, A. Saxena, S. Chattopadhyay, and T. Mondal, “Influence of nanofillers on adhesion properties of polymeric composites,” ACS Omega, vol. 7, no. 5, pp. 3844–3859, 2022. DOI: https://doi.org/10.1021/acsomega.1c05448

Z. Osman, M. Elamin, E. Ghorbel, and B. Charrier, “Influence of alkaline treatment and fiber morphology on the mechanical, physical, and thermal properties of polypropylene and polylactic acid biocomposites reinforced with Kenaf, Bagasse, Hemp Fibers and Softwood,” Polymers, vol. 17, no. 7, p. 844, 2025. DOI: https://doi.org/10.3390/polym17070844

Y. Feng, H. Hao, H. Lu, C. L. Chow, and D. Lau, “Exploring the development and applications of sustainable natural fiber composites: A review from a nanoscale perspective,” Composites Part B: Engineering, vol. 276, p. 111369, 2024. DOI: https://doi.org/10.1016/j.compositesb.2024.111369

G. V. Jasgurpreet, S. Chohan, R. S. Ramesh, V. R. Ranjith, and K. D. Elil, “Exploring mechanical and flammability traits in hybrid composites of crown flower/nano­SiO2/4ZnO·B2O3·H2O under cryogenic conditions : An experimental study,” Silicon, vol. 16, no. 8, pp. 1‒15, 2024. DOI: https://doi.org/10.1007/s12633-024-02926-9

N. S. Karaduman, “Experimental investigation of the effect of weave type on the mechanical properties of woven hemp fabric/ epoxy composites,” Journal of Composite Materials., 56, no. 8, pp. 1255–1265, 2022. DOI: https://doi.org/10.1177/00219983221075416

F. M. Hassan, and H. H. Darwoysh, “Scanning electron microscopy study for fracture surface of epoxy/Al2O3 nanocomposites,” International Journal of Scientific & Engineering Research, vol. 6, no. 12, pp. 286–289, 2015.

W. Shanthi, G. Ramakrishna, M. Bakkiyaraj, A. Surenderpaul, G. A. Sivasankar, R. Velumayil, S. Palanisamy, and B. Palanikumar, “Enhancement of mechanical properties in hybrid hemp-epoxy composites with nano-silicon dioxide and nanographene fillers,” in AIP Conference Proceedings, vol. 3270, no. 1, p. 20251, 2025. DOI: https://doi.org/10.1063/5.0261764

V. Ganesan, V. Shanmugam, and V. Alagumalai, “Optimisation of mechanical behaviour of calotropis gigantea and prosopis juliflora natural fibre-based hybrid composites by using Taguchi-Grey relational analysis,” Composites Part C: Open Access, vol. 13, p. 100433, 2024. DOI: https://doi.org/10.1016/j.jcomc.2024.100433

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Published

2026-05-20

How to Cite

[1]
V. GANESAN, J. S. . CHOHAN, M. . V, N. M, and L. N. . S, “Advanced hemp-based hybrid composites: A study on the influence of various nanofillers on mechanical and morphological properties”, J Met Mater Miner, vol. 36, no. 2, p. e2427, May 2026.

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