Synthesis, structure, and electrochemical properties of the Ni(OH)\(_{2}\)/NiMoO\(_{4}\) composite on the rGO/NF template for hybrid battery-supercapacitor electrodes

Retno ASIH; Haniffudin  NURDIANSAH; Rogabe  SIANIPAR; Ida Ayu  GAYATRI; Lukman  NOEROCHIM; Diah  SUSANTI; Isao  WATANABE; Darminto DARMINTO

doi:10.55713/jmmm.v36i1.2309

ผู้แต่ง

Retno ASIH Department of Physics, Institut Teknologi Sepuluh Nopember, Surabaya, 60111, Indonesia
Haniffudin NURDIANSAH Department of Material and Metallurgical Engineering, Institut Teknologi Sepuluh Nopember, Surabaya, 60111, Indonesia
Rogabe SIANIPAR Department of Material and Metallurgical Engineering, Institut Teknologi Sepuluh Nopember, Surabaya, 60111, Indonesia
Ida Ayu GAYATRI Department of Material and Metallurgical Engineering, Institut Teknologi Sepuluh Nopember, Surabaya, 60111, Indonesia
Lukman NOEROCHIM Department of Material and Metallurgical Engineering, Institut Teknologi Sepuluh Nopember, Surabaya, 60111, Indonesia
Diah SUSANTI Department of Material and Metallurgical Engineering, Institut Teknologi Sepuluh Nopember, Surabaya, 60111, Indonesia
Isao WATANABE Nuclear Structure Research Group, RIKEN Nishina Center, 2-1 Hirosawa, Wako, Saitama, 351-0198, Japan
Darminto DARMINTO Department of Physics, Institut Teknologi Sepuluh Nopember, Surabaya, 60111, Indonesia

DOI:

https://doi.org/10.55713/jmmm.v36i1.2309

คำสำคัญ:

electrochemical performance, electrode, hybrid battery-supercapacitor, Ni(OH)2/NiMoO4/rGO/NF

บทคัดย่อ

The growing demand for renewable and sustainable energy has intensified research on advanced energy-storage systems that can deliver both high energy and power densities. In this study, a Ni(OH)₂/ NiMoO₄ composite on a reduced graphene oxide/nickel foam (rGO/NF) template was synthesized through a hydrothermal and electrodeposition route to construct a hybrid battery-supercapacitor electrode. The unique hierarchical design combines the pseudocapacitive activity of Ni(OH)₂/NiMoO₄ with the excellent conductivity of rGO and the high surface area of NF, enabling efficient electron and ion transport. Structural and morphological analyses confirm the successful formation of the Ni(OH)₂/NiMoO₄/rGO/NF architecture. The electrode exhibits a specific capacitance (C_s) of ~358 F∙g^‒1 at 5 mV∙s^‒1, an energy density of ~24 Wh∙kg^‒1, a power density of ~626 W∙kg^‒1, a conductivity of 1.30 S∙m^‒1 (0.01 kHz), and retains ~86% capacitance after 50 cycles. These findings demonstrate that the synergistic integration of multiredox Ni(OH)₂/NiMoO₄ with conductive rGO/NF enhances electrochemical performance, providing effective design strategy for developing hybrid battery-supercapacitor electrodes.

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